In what is one of the standout ties of the round, Barcelona have been handed a tricky reunion with Paris Saint-Germain in the Champions League last 16, with fellow LaLiga sides Real Madrid, Atletico Madrid and Sevilla given slightly more favourable fixtures in the Nyon draw.
Holders Real, who finished second in Group F, are set to play Maurizio Sarri's Napoli in the knockout stage, while city neighbours Atletico will once again meet Bayer Leverkusen in a re-run of last season's tense clash.
Sevilla were also given an eminently winnable tie, with the Rojiblancos avoiding some of Europe's leading lights to finally be paired with faltering Premier League winners Leicester City.
First-leg matches will take place on either the 14/15 February or 21/22, with second-leg games pencilled in for the beginning of March.
Champions League Round of 16 draw
Manchester City-Monaco
Real Madrid-Napoli
Benfica-Borussia Dortmund
Bayern-Arsenal
Porto-Juventus
Bayer Leverkusen-Atletico Madrid
Sevilla-Leicester
PSG-Barcelona
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